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meso-Tetraphenylporphine-Au(III) chlorid


Structure: (click to enlarge, please!)

Structure of meso-Tetraphenylporphine-Au(III) chlorid
Quantities Sold:  
100 mg 445 €
250 mg 635 €
1 g 1905 €
Data:  
Synonym: TPP-Au(III)Cl
Part Number: PL00017917
CAS: 15695-27-9
Molecular Formula: C44H28AuClN4
Molecular Weight: 845.1384
Melting Point: no information
Solubility: Dichlormethane, Chloroform

UV/VIS-Spectrum: (click to enlarge, please!)

spectrum of meso-Tetraphenylporphine-Au(III) chlorid

Informationen zum Einsatz von 

TPP-Au(III)Cl:

This porphyrin stabilized gold (III) as a metalloporphyrin. It has in vitro and in vivo cytotoxicity against tumor cells. Further [Au (TPP)]Cl shows a high catalytic activity.


Examples from the literature:

1.) To Y.F., Sun R.W., Chen Y., Chan V.S., Yu W.Y., Tam P.K., Che C.M. and Lin C.L., Gold(III) porphyrin complex is more potent than cisplatin in inhibiting growth of nasopharyngeal carcinoma in vitro and in vivo., Int. J. Cancer, 124, 2009, 1971-1979
2.) A. Nijamudheen , Deepthi Jose and Ayan Datta, Why Does Gold(III) Porphyrin Act as a Selective Catalyst in the Cycloisomerization of Allenones?, J. Phys. Chem, 115, 2010, 2187-2195